CT shifts resonance · CM sets 50 Ω match · they couple, so tune iteratively.
The NMR probe contains a solenoid RF coil around the sample tube. Tuning means lining up the spectrometer frequency with the probe's resonant circuit so RF power enters the probe efficiently instead of reflecting back.
Tuning capacitor (CT) moves the dip left or right by shifting the probe resonance toward the target frequency.
Matching capacitor (CM) deepens the dip by matching the probe to the 50 Ω transmission line.
- Move CT to bring the dip toward the target frequency.
- If the dip is too far left, lower CT. If it is too far right, raise CT.
- Move CM to make the dip deeper once it is near the target.
- Use small steps and go back and forth between CT and CM.
- Stop when the dip is centered on the target and is as deep as possible.
⚙️ Tuning Capacitor (CT)
⚙️ Matching Capacitor (CM)
🧪 Sample Dielectric
🎯 Target Frequency
The probe's LC circuit resonates at:
f = 1 / (2π√(LC))where L is the coil inductance and C is the total circuit capacitance (tune + match in network). Adjusting CT shifts this frequency.
The reflection coefficient Γ measures impedance mismatch:
Γ = (ZL − 50) / (ZL + 50)Return Loss in dB:
RL = −20 log₁₀|Γ|Deeper dip (more negative dB) means better matching. Less RF power is reflected.
Voltage Standing Wave Ratio:
VSWR = (1 + |Γ|) / (1 − |Γ|)VSWR = 1.0 is perfect. VSWR < 1.5 is excellent for NMR. High VSWR means standing waves on the cable that waste power and can damage amplifiers.
The nuclear spin precession frequency in a magnetic field B₀:
f₀ = γ · B₀ / (2π)¹H NMR: γ/2π = 42.577 MHz/T → at 9.4 T → 400 MHz
¹³C NMR: γ/2π = 10.708 MHz/T → at 9.4 T → 100.6 MHz
This is the frequency your probe must be tuned and matched to.